Applied Physics
Husam Nahedh; Odai N. Salman; Mukhlis M. Ismail
Abstract
In this study, sodium bismuth titanate ferroelectric ceramics with a nanoscale structure and low iron content (NBTF) were prepared, providing an alternative to lead-based materials. Lead poses environmental and health risks due to its toxicity. NBTF aims to develop a more sustainable ferroelectric composition. ...
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In this study, sodium bismuth titanate ferroelectric ceramics with a nanoscale structure and low iron content (NBTF) were prepared, providing an alternative to lead-based materials. Lead poses environmental and health risks due to its toxicity. NBTF aims to develop a more sustainable ferroelectric composition. The structural, optical, and electrical properties of Na0.5Bi0.5Ti1-xFexO3-0.5x (x=0.06) were investigated. X-ray diffraction revealed the material crystallizes in the rhombohedral phase, with crystallite size of approximately 19.1 nm in size. Infrared and Raman spectroscopy confirmed the formation of a perovskite structure containing Fe ions, evidenced by Ti-O stretching and O-Fe-O bending vibrations. Raman spectroscopy also identified a broad peak at high frequencies, suggesting the generation of oxygen vacancies induced by the dopant. Electrical characterization demonstrated semiconductor behavior with a bandgap of 1.84 eV, showing potential for optoelectronic applications. The study focused on the effect of oxygen vacancies on electrical conductivity. Furthermore, a nano-perovskite heterojunction photodiode comprising Al/p-Si/NBTF/Ag was successfully fabricated and evaluated. Under reverse bias, photocurrent increased compared to the dark state with rising illumination intensity. Device parameters including reaction order, ideality factor, and carrier lifetime were calculated. Collectively, these results indicate promise for integrating this heterostructure photodiode into electronic circuitry applications.
Applied Physics
Adam K. kadhim; Atheer I. Abd Ali; Mohammad R. Mohammad
Abstract
In this paper, we present triple cation perovskites because it has excellent stability and PV performance. To characterize the triple-cation perovskite solar cells, X-ray diffraction, Field emission scanning electron microscope, and Ultraviolet-visible spectroscopy were used. The performance of perovskite ...
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In this paper, we present triple cation perovskites because it has excellent stability and PV performance. To characterize the triple-cation perovskite solar cells, X-ray diffraction, Field emission scanning electron microscope, and Ultraviolet-visible spectroscopy were used. The performance of perovskite solar cells was improved by reducing graphene oxide/bismuth oxide mixed mesoporous titanium dioxide as an effective electron transport layer. The perovskite layer deposited onto modified TiO2 layer showed a larger grain size with better crystalline nature. The optimum device has fabricated at room temperature without a glove box and obtained a power conversion efficacy of 17%.
